Well, some PBT keycaps are much thicker. See, for example, the thick PBT that Imsto is currently selling in the Group buys forum, or cherry (their PBT is supposed to be pretty thick). Also, ABS can be thick: See old WYSE keycaps or the ABS on my IBM selectric.
But in this case, PBT refers just to the type of plastic used. Lots of people prefer thick, though.