I hate to be that guy, but there are tons of different plastics that could be used but are not. So there are many non-standard options in that category too.
It seems like everything is either plastic, acrylic or aluminum.
It's like if this statement read "It seems like everything is either plastic or metal". There are tons of types of plastic, just as there are tons of types of metal.
Anyway, that aside, AFAIK most plastic cases are injection moulded ABS or CNCed acrylic. It would be interesting to see how some other polymers handle being moulded into keyboard cases... Like HIPS, or PET... That would be fun.
Matias uses injection moulded PC, which is also quite common for apple products of a certain age. I think CNC PMMA is used for less KBs than (say) aluminium. I only know of reaper's HHMX, that TEX one, and maybe another custom. Lasered PMMA (the cheat, etc.) is more common, especially for layer cases (hhmx, litster, ergodox, etc )
There's been keycaps made in the following polymers:
ABS/PBT/POM/Nylon, and a few others (especially for non cherry keyboards)
Now I'd love to see a FR PC+ABS like what they make laptop computers from. Also, a PIM magnesium (also used in computers by lenovo, hp, fujitsu, etc) case would be sweet.
sadly tooling for these would be expensive, so they'll likely never get made,
Other than that my great hope is glass (yes I saw them) and ceramic (particularly Al2O3!) keycaps.
Ceramic is a possibility, at least for keypads. I am considering making a 3d printed ceramic one for my GHpad.
I am
very interested in this.
Uranium ore
far too brittle. pitchblende is not the best structural material.
Now DU (Depleted Uranium) on the other hand... That has possibility. It's extremely expensive, however.
Copper anyone?
You'd have to insulate it but it would look brilliant!
See, I'd purposely oxidize the copper to let the verdigris out. It's make a sick matte green case, imo.