1 unit is 0.750", or 19.05mm.
In some instances, you may see 1.25 unit caps (for example) written as 1.2 unit -- this is usually just due to truncation, and should still reflect a 1.25 unit keycap.
Signature plastics sells keys in their pimpmykeyboard keyshop:
http://keyshop.pimpmykeyboard.com/I don't know if you can actually find a spacebar of 4 units. It depends on what moulds are available. You could contact signature plastics (a keycap manufacturer) and ask what dimensions they have available for keys. Most keys are made more complicated by row profiles. The keys on your keyboard are likely sculpted to approximate a curve when sloping along a flat surface. This causes each row of keys to have a different profile. All keycap lengths may not be available in all profiles. Spacebars usually are in their own profile, due to being convex rather than concave. This should be a mostly complete list of what is available for spacebars, not sure about other keys:
http://deskthority.net/wiki/Space_bar_dimensionsIf a mould does not exist for a particular keycap or legend, it may be possible (with some manufacturers) to create a mould, however this can be expensive. If you want a single keycap made, or a small run, this can also be expensive, as there are setup costs associated with making a run of caps, which are constant no matter how many caps are being made.
There's probably a lot more to it than this -- I don't know a ton about keycap manufacturing.