If you still enjoy your slick doubleshots (like me) then they will probably take at least a decade to wear out (Depending on how much you use them). I have a moder F, like foghat.digs, and the keys show little (if any) shine. Even the spacebar has it's full texture. The keycaps do have a different texture compared with my new unicomp keycaps (also PBT). I prefer the older ones, but the new ones are also great.
Dyesub PBT is also not for the feint of wallet, but it is by far my favourite plastic for keycaps. I haven't tried Nylon (zowie, celeritas I think?) or Polycarbonate (feng's limited edition clear blanks) though.
Moulding metal is indeed usually pretty different than plastic, but PIM (Powder Injection Moulding) is still somewhat similar across metal, ceramic, and plastic, though oftentimes, you need a vacuum oven to prevent oxidation (burning).