I wouldn't say that I'm more knowledgeable, but i can say that the black is the flux/rosin.
For the led problem, there is too much solder on the led pads (the top pair) which are probably shorting to the ground screen (the cross-hatch pattern). Now I'm making the assumption that the ground screen is connected to ground.

To attempt to rectify this? I would desolder the led with a sucker or wick and ensure there aren't any joining dags of solder left behind, maybe even run around the space between the pads and ground screen with an art knife or the like.
Then power up the kb and test to see if the previously working leds are operating again.
If they are working, resolder the down arrow led being careful to not produce a large 'blob'.
Now, if the other leds are still inoperative after desoldering the offender, then it would involve tracing the tracks back to see if the group of leds run off the one dropping resistor and testing/replacing it.