PSN only applies to some Intel P6 (Pentium III, Celeron "II") processors, I think Intel completely abandoned it from Pentium 4 onwards.
According to
this site the PSN (if present) is a parameter that's used in the "formula" which calculates the GUID string. It looks like basically all unique SMBIOS and firmware which software can read gets involved.
I remember buying a new AGP card and reflashing my memory SPD firmware to bump default timing/voltages a little (to enjoy higher performance gain from my new hardware). XP decided that I'd changed "5 pieces of hardware", thus forcing me to endure hours of 1-800-Microsoft bull****.
I think my, uh, deactivator software is a warez. Can't find anything of the sort on Technet (although there are XP keygens).