AFAIK, you can have PBT double-shots.
PBT is a material, double-shot is a molding technique.
People also like double-shots due to the quality of the lettering, and that it can be any color.
Topre uses dye sublimation, which also makes good quality lettering, and can do multiple colors on one keycap, but it can only be darker than the plastic - hence the black/black. (This, by the way, is also why you can't easily get black lettered keys on a buckling spring keyboard - double shots are impractical due to how buckling spring keys are made, dye sublimation can only do black/black, pad printing is poor durability (but it's what was done for the black Model M13, and some early black Unicomp boards), and nobody's tried lasering (but that should work).)