Shield and brown wires are usually connected together, so consider them one wire. It's easy to spot because connected to the metal parts of your pc and your keyboard.
Once you have ground, 5V is easy to find, even if you don't have great experience, you should see one or more electrolytic capacitors connected between it and ground.
The last wires are the data ones, if you connect them reversed the keyboard don't work but you don't burn anything.
The PS2 or AT connectors pinout are easy to find with google.
Btw post a photo of front and back of PCB so I can be more precise