Not familiar with the board, but skimming the specs this stands out:
N Key Rollover: Gaming cluster with anti ghosting capability
With a proper NKRO board, no area needs special attention. Mentioning the gaming cluster at all hints that the keyboard doesn't have the diodes required to get full NKRO.
That said, with an optimized matrix the WASD keys and those around them should be fine. So there's a couple of possibilities - either you're using a combination that blocks, or there might actually be a fault in one of the switches (since you say "it doesnt happen all the time"). I suggest testing with a key test program like aquakeytest to figure out exactly what switch or combination gives the problem.