Thanks for the insight everyone, it saved me some time and a little cash.
I just read a writeup at ClickyKeyboards on this issue and thought that I should give the definitive end to this question (you can't add native ps2 using these cards), thus killing the hopes of anyone hoping to find a way to add native ps2 to a non-ps2 mobo.
from clickykeyboards.com:
Question: I am very familar with ’puters and am good with a screwdriver and I know how to open my computer. Why can’t I buy an expansion card with a ps/2 port that fits into a PCI slot. I have seen these before on my computers at work and they must be readily available.
A. As a corporate IT admin and systems engineer in real-life, I have seen Dell computers with ps/2 ports on the back of computers where the PCI slot covers are. However, this specialized part sold by Dell (part# F3636) was only intended to be used with certain Dell Optiplex computers. This part does not actually plug into any PCI slots of the motherboard, but insteads uses a 24-pin ribbon cable to connect directly to a special connector on certain Dell Optiplex motherboards.
The keyboard interface is an elementary low-level device and it needs to be initalized very early during the boot process. Any true PC hardware geek with real-world experience knows that the PCI bus is not setup and cannot be used to capture the type of direct, low-level I/O signals between the keyboard and computer.
It's humbling, but there you have it.
The best choice is a ps2 to usb converter (as opposed to just an adapter), there's great info on that
here. This is probably just a big DUH! for most of you.