lubricatet the tools with vaseline / petrolium jelly .. that will smooth the surface.
i usualy sculp with greenstuff or apoxy sculpt and that works just right
as for silicon / resin i use
https://www.dwrplastics.com slow curing resin 2h is good enough .. thats not the only expense and to be fair thats the cheap stuff .. you do need a vac chamber and a pressure pot to even consider propper casting .. otherwise you will catch a ton of airbubbles
so its around 1000 usd at the LOW gear end
+ you need safty gear as well hope you dont have pets - resins are not exactly healthy